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991.
Some new inequalities of Hermite-Hadamard's integration are established.As for as inequalities about the righthand side of the classical Hermite-Hadamard's integral inequality refined by S Qaisar in [3],a new upper bound is given.Under special conditions,the bound is smaller than that in [3]. 相似文献
992.
993.
Mateusz Maciejewski Paul N. Barlow Nico Tjandra 《Journal of computational chemistry》2014,35(7):518-525
In this study, we examine the feasibility and limitations of describing the motional behavior of three‐domain proteins in which the domains are linearly connected. In addition to attempting the determination of the internal and overall reorientational correlation times, we investigate the existence of correlations in the motions between the three domains. Since in linearly arranged three‐domain proteins, there are typically no experimental data that can directly report on motional correlation between the first and the third domain, we address this question by dynamics simulations. Two limiting cases occur: (1) for weak repulsive potentials and (2) when strong repulsive potentials are applied between sequential domains. The motions of the terminal domains become correlated in the case of strong interdomain repulsive potentials when these potentials do not allow the angle between the sequential domains to be smaller than about 60°. Using the model‐free (MF) and extended MF formalisms of Lipari and Szabo, we find that the motional behavior can be separated into two components; the first component represents the concerted overall motion of the three domains, and the second describes the independent component of the motion of each individual domain. We find that this division of the motional behavior of the protein is maintained only when their timescales are distinct and can be made when the angles between sequential domains remain between 60° and 160°. In this work, we identify and quantify interdomain motional correlations. © 2013 Wiley Periodicals, Inc. 相似文献
994.
In this paper we study the nonlinear Chern–Simons–Schrödinger systems with an external potential. We show the existence, non-existence, and multiplicity of standing waves to this problem with asymptotically linear nonlinearities, which do not hold the Ambrosetti–Rabinowitz condition. 相似文献
995.
The concept of the quantum Pfaffian is rigorously examined and refurbished using the new method of quantum exterior algebras. We derive a complete family of Plücker relations for the quantum linear transformations, and then use them to give an optimal set of relations required for the quantum Pfaffian. We then give the formula between the quantum determinant and the quantum Pfaffian and prove that any quantum determinant can be expressed as a quantum Pfaffian. Finally the quantum hyper-Pfaffian is introduced, and we prove a similar result of expressing quantum determinants in terms of quantum hyper-Pfaffians at modular cases. 相似文献
996.
997.
Chitosan/Ce(IV) redox polymerization‐based amplification for detection of DNA point mutation 下载免费PDF全文
Yanjun Cui Tianwei Tan Jing Yang 《Journal of polymer science. Part A, Polymer chemistry》2016,54(13):1929-1937
Polymerization‐based signal amplification, a technique developed for use in rapid diagnostic tests, hinges on the ability to localize initiators as a function of interfacial binding events. We report here a new DNA detection method in which polymer growth in redox‐polymerization is used as a means to amplify detection signals. The introduction of biotin‐labeled chitosan (biotin‐CS) with highly dense amino groups into the polymerization amplification as macromolecular reducing agent, beneficially simplifies amplification operation, as well as, provides a large amount of initiation points to improve the sensitivity of detection. DNA hybridization, SA and biotin binding reactions led to the attachment of CS on a solid surface where specific DNA sequences were located. With the addition of the mixture containing monomer AM, crosslinker PEGDA and oxidant CAN onto the CS location, the growth of polymer films was triggered to render the corresponding spots readily distinguishable to the naked eye. Direct visualization of 0.21 fmol target DNA molecules of interest was demonstrated. Non‐small cell lung cancer p53 sequence was further selected as a proof‐of‐principle to detect DNA point mutation. The proposed method exhibited an efficient amplification performance for molecule detection, and paved a new way for visual diagnosis of biomolecules. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 1929–1937 相似文献
998.
999.
We investigate the behavior of optical absorption of boron–nitride nanotubes (6,0) in the context of Hubbard model at the paramagnetic sector. GW approximation has been implemented in order to make self-energy matrix of electronic system. Afterwards, the real and imaginary parts of transverse dielectric functions have been obtained using linear response theory. The results show that the frequency gap in the optical absorption decreases with Coulomb repulsion strength. Moreover the results show that the local Coulomb interaction leads to the appearance of the excitonic effects in the optical spectrum. Finally the effects of electronic concentration on the frequency behavior of imaginary part of dielectric function have been investigated. 相似文献
1000.
《Journal of Coordination Chemistry》2012,65(18):1965-1972
New metal-free phthalocyanine (7) fused symmetrically in peripheral positions with four dithiatetraoxa macrocycles, has been synthesized by cyclotetramerization of the isoindolinediimine derivative of macrocyclic 6. Metallophthalocyanine (8) was synthesized by reaction of phthalonitrile derivative (5) with anhydrous nickel(II) chloride. The new compounds were characterized by elemental analysis, 1H and 13C-NMR, IR UV–Vis and mass spectroscopies. 相似文献